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锂离子电池硅负极材料衰退机理的研究进展

马增胜 周益春 刘军 薛冬峰 杨庆生 潘勇

马增胜, 周益春, 刘军, 薛冬峰, 杨庆生, 潘勇. 锂离子电池硅负极材料衰退机理的研究进展[J]. 力学进展, 2013, 43(6): 581-599. doi: 10.6052/1000-0992-13-066
引用本文: 马增胜, 周益春, 刘军, 薛冬峰, 杨庆生, 潘勇. 锂离子电池硅负极材料衰退机理的研究进展[J]. 力学进展, 2013, 43(6): 581-599. doi: 10.6052/1000-0992-13-066
MA Zengsheng, ZHOU Yichun, LIU Jun, XUE Dongfeng, YANG Qingsheng, PAN Yong. Research progress in degradation mechanism of silicon anode materials for lithium-ion batteries[J]. Advances in Mechanics, 2013, 43(6): 581-599. doi: 10.6052/1000-0992-13-066
Citation: MA Zengsheng, ZHOU Yichun, LIU Jun, XUE Dongfeng, YANG Qingsheng, PAN Yong. Research progress in degradation mechanism of silicon anode materials for lithium-ion batteries[J]. Advances in Mechanics, 2013, 43(6): 581-599. doi: 10.6052/1000-0992-13-066

锂离子电池硅负极材料衰退机理的研究进展

doi: 10.6052/1000-0992-13-066
基金项目: 国家自然科学基金(11102176, 11372267);国家高技术研究发展计划(863 计划)(2013AA032502);湖南省战略性新兴产业(2012GK4075)资助项目
详细信息
    通讯作者:

    周益春,潘勇

    周益春,潘勇

  • 中图分类号: TM912

Research progress in degradation mechanism of silicon anode materials for lithium-ion batteries

Funds: The project was supported by the National Natural Science Foundation of China (11102176, 11372267), the National High Technology Research and Development Program of China (863 Program) (2013AA032502), and the Emerging Strategic Industries of Hunan Province (2012GK4075).
More Information
    Corresponding author: ZHOU Yichun; PAN Yong
  • 摘要: 硅负极材料由于具有非常高的理论比容量,使之成为锂离子电池极具前景的负极替代材料,然而,硅负极材料在充放电过程中会发生非常大的体积变形,这会引起活性材料的破坏失效,严重影响其电化学循环性能,成为制约其在锂离子电池领域广泛应用的最大瓶颈,本文介绍了硅负极材料的不同结构形态及其在充放电过程中电化学性能的退化机理,并综述了充放电过程中的力学性能演化、相关理论分析、数值模拟计算等方面的最新国际研究进展,展望了硅负极材料力学失效方面的研究重点,

     

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  • 收稿日期:  2013-09-01
  • 修回日期:  2013-10-22
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